Organic Chemistry

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Across
  1. 1. reactant that donates electrons to form a new bond
  2. 3. not chiral. A compound (or object) that is superimposable on its mirror image
  3. 5. stabilizing interaction that results from the interaction of the electrons in a sigma-bond with an adjacent empty or partially filled p-orbital or a π-orbital to give an extended molecular orbital that increases the stability of the system
  4. 8. neutral dipolar molecule containing a negatively charged atom directly attached to a positively charged heteroatom
  5. 9. if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change to reestablish an equilibrium
  6. 10. a conformation in which substituents on two attached saturated carbon atoms overlap when viewed as a Newman projection
  7. 11. Aldehyde and an Alcohol that is catalytic
  8. 12. rule that whenever it is possible, an elimination reaction will favor the formation of the most stable double bond
  9. 13. stability
  10. 14. a term that may be applied to any asymmetric object or molecule
  11. 16. a reactant that accepts electrons to form a new bond
  12. 17. stereoisomeric structures which do not mirror images of one another
  13. 21. The effect on electron density in one portion of a molecule due to electron-withdrawing or electron-donating groups elsewhere in the molecule
  14. 23. a set of rules that determines whether a compound is aromatic or not
  15. 24. preparation of two pure enantiomers from a single chiral carbon
  16. 25. carbon atom gains bonds to more electronegative elements
  17. 26. any effect due to the size of atoms or groups
Down
  1. 2. a substance that, when added to a reaction mixture, changes the rate of attainment of equilibrium in the system without itself undergoing a permanent chemical change
  2. 4. occurs between multiple molecules
  3. 6. increase in number of bonds between atoms that are less electronegative
  4. 7. occurs within a molecule
  5. 10. deprotonated anions of enols
  6. 13. has a hydroxyl group directly bonded to an alkene
  7. 15. an equimolar mixture of the two enantiomeric isomers of a compound, equal chance of adding to top or bottom
  8. 18. when a lone pair is next to an empty p-orbital
  9. 19. the addition of the elements of water to a substance
  10. 20. interconvert with one another
  11. 22. randomness