Best crosswrod made evr

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Across
  1. 3. Karl Ussher
  2. 5. Objectively nonsense or primordial deity personifying time
  3. 9. Scalar associated with a linear transformation’s invariant vectors
  4. 10. Annoying streaming quirk
  5. 12. Emission of electrons due to incident radiation
  6. 16. Fundamental limit relating conjugate variables
  7. 18. Slot 10 in a 2 wafer FOUP (requal)
  8. 19. Euromillions
  9. 21. "No Opps Left Behind" rapper
  10. 22. Best movie of OAT (fact)
  11. 25. WhAt To NoT dO iF oNe WiNs ThE lOtTo
  12. 26. Mormon practice
  13. 27. Best franchise OAT according to some (debatable)
  14. 28. Many a man doth long for my demise (artist)
  15. 30. Friday at the end of a block of 3 days (second half of the year)
  16. 31. Biggest government psyop ever
  17. 33. History-dependent response in materials or systems
  18. 37. Momentum-dependent wavelength of matter
  19. 39. Thermal repair of lattice damage
  20. 41. Evil genius
  21. 42. Peak vehicular engineering (fact)
  22. 43. Most useful software (fr)
  23. 45. Decomposition of a signal into frequency components
Down
  1. 1. Single-crystal layer grown on a substrate
  2. 2. Blackbody radiation spectral law
  3. 4. Viral dual-release phenomenon redefining moviegoing
  4. 6. Failsafe to go back to better times
  5. 7. midday
  6. 8. Not yet proven scientifically
  7. 11. Jupiters largest moon
  8. 13. Fourth deadly sin
  9. 14. Energy at which electron occupation probability is one half
  10. 15. Second in a 'three' horse race
  11. 17. Chinese 'propaganda' software
  12. 20. Divergence of the gradient of a scalar field
  13. 23. Lateral strain divided by axial strain
  14. 24. Overwhelming feeling one experiences hours before starting a block of 4
  15. 29. Most followed streamer 2025
  16. 32. Built differently
  17. 34. "I'd rather go blind" singer
  18. 35. Charlotte Hornets player who unknowingly started meaningless viral trend
  19. 36. Low IQ individuals (close to home)
  20. 38. Teddy bear (Endor)
  21. 40. Objectively bottom tier on Maslow's hierarchy of needs
  22. 44. Correct political party (Ireland)