CARBONYL CHEMISTRY

4. Enol form is preferred over a keto form mostly in cases of _________ hydrogen bonding
7. Benzaldehyde in the presence of potassium cyanide undergoes a type of condensation reaction to give this product
9. Primary reactant of Benzil-Benzilic Rearrangement.
11. Preparation of Phosphorus ylide in wittig reaction involves a SN ___ attack by triphenyl phosphine on an alkyl halide (in words)
12. A non aromatic nitrogen containing base used in Knoevenagel Condensation
14. A stronger oxidising agent than Pyridinium dichromate (PDC) and more acidic in nature (Pyridinium ___________)
15. This ester CANNOT undergo ketonic hydrolysis (common name)
19. Common reagent in MPV Reduction is Aluminium __________
20. When intra or intermolecular proton exchange takes place in a mechanism, it is called ___________ interconversion (hint: mobile atom is a proton)

1. Alcohols and ketones without terminal ________ group cannot undergo haloform reaction
2. Benzaldehyde reacts with acetic anhydride in the presence of sodium acetate to give this acid
3. Avery well known reagent for Baeyer Villiger oxidation, known to give rapid reaction due to its high electron withdrawing tendency ( name of the peracid)
5. Type of addition reaction where a carbanion nucleophile attacks an alpha,beta-unsaturated carbonyl compound: _________ Addition
6. The cyclic intermediate in Wittig reaction formed by cyclo addition of the reactants
8. General name of the nucleophilic intermediate produced in the first step of aldol condensation
10. Acetone + Iodine + Potassium hydroxide ---> pale yellow ppt. Reaction name is _______
13. An acid sensitive carbonyl compound will be converted to alkane using this reduction.
16. Cannizaro Reaction takes place in the absence of ______ hydrogen in the carbonyl compound
17. Cyclohexanone reacts with hydroxylamine in the presence of sulphuric acid to give (common name)
18. Mechanism of converting aldol products back to its predecessor aldehyde or ketone: _______ aldol