COORDINATION COMPOUNDS

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Across
  1. 2. A method used to differentiate cis/trans isomers of [Pt(NH3)2Cl2].(9)
  2. 5. [Co(NH3)6]3+ is an _______ orbital complex.(5)
  3. 7. Complexes in which the central metal atom is bound to only one kind of ligand are called ________ complexes.(10)
  4. 9. Permanganate complex is coloured due to Ligand to Metal _______ transfer phenomenon.(6)
  5. 11. Anionic groups in a complex can satisfy both primary and secondary valencies and are said to perform a _______ function.(4)
  6. 13. Geometry of a complex with coordination number 7 is ________ bipyramidal.(10)
  7. 16. Full name of the acac ligand.(15)
  8. 18. The principle applied in the formation of [FeF6]3- and results in its stability.(17)
  9. 19. The crystal field splitting ________ with the increase in the principal quantum number of the valence shell of the metal atom.(9)
Down
  1. 1. Total number of stereoisomers in an [Mabcdef] type of complex. (hint: in words)(6)
  2. 3. Geometry having the highest CFS value (del).(12)
  3. 4. Number of stereoisomers of [M(pn)2Cl2]+
  4. 6. Carbonyl is a pi-______ ligand.(8)
  5. 8. Number of pairing energy required for a d6 configuration under the influence of a strong field ligand.(3)
  6. 10. [Ni(H2O)6]2+ has a magnetic moment of sq. root (_______) B.M.(5)
  7. 11. Number of donor atoms in a complex.(9)
  8. 12. The energy level of a complex under the influence of a hypothetical spherically symmetrical ligand field is called _______ centre. (5)
  9. 14. CoCl3.5NH3 when treated with silver nitrate solution, gives _______ moles of silver chloride precipitate. (3)
  10. 15. Exchange of ligand groups within the coordination sphere of a bridge complex is called Coordination _______ isomerism.(8)
  11. 17. The ions that constitute the ionic sphere in a complex are called ______ ions.(7)