Coordination compounds
Across
- 3. The region around the central atom where ligands donate electron density.
- 6. The hypothetical charge an atom would have if all bonds to atoms of different elements were 100% ionic.
- 8. Complexes with maximum unpaired electrons due to weak-field ligands.
- 13. Complexes with paired electrons due to strong-field ligands.
- 14. A ligand that can coordinate through two different atoms but only one at a time.
- 15. A ligand that has two donor atoms to bind to a central metal.
- 17. The number of ligand donor atoms bonded to the central metal atom or ion.
- 19. Involves d-orbitals from the (n-1)th shell during bonding in low-spin complexes.
- 20. The pairing of electrons in the same orbital due to ligand field effects.
- 21. The effect of the electric fields created by ligands on the d-orbitals of the central metal ion.
- 22. The energy difference between d-orbitals in a ligand field.
- 23. A pair of electrons that is shared between atoms or donated by a ligand.
- 24. Equilibrium constant for the formation of a complex from its components.
- 25. Occurs when a ligand can coordinate to the metal in two different ways.
- 26. Different arrangements of atoms that result in different compounds.
- 27. Replacement of one ligand in a complex with another.
- 28. Isomerism in which isomers are non-superimposable mirror images.
- 29. Theories that describe bonding in coordination compounds such as CFT or MOT.
Down
- 1. The atom in a ligand that donates a lone pair to the metal center.
- 2. Isomerism due to the exchange of water molecules inside and outside coordination sphere.
- 4. Isomerism in coordination compounds due to different spatial arrangements around the metal.
- 5. Isomerism due to different spatial arrangements of ligands.
- 7. Isomerism arising from exchange of ligands between cationic and anionic complexes.
- 9. An empirical arrangement of ligands based on the strength of the field they generate.
- 10. The central metal atom/ion and the ligands directly attached to it.
- 11. A ligand with multiple donor atoms that can bind to a metal ion.
- 12. A ligand that forms more than one bond with a single metal ion.
- 16. Involves d-orbitals from the nth shell during bonding in high-spin complexes.
- 18. Isomers produce different ions in solution though their composition is same.
- 21. An electronic transition between metal and ligand orbitals involving charge redistribution.