Final Review Game
Across
- 2. A unimolecular nucleophilic substitution reaction
- 5. The position immediately adjacent to a functional group.
- 7. An intermediate containing a positively charged carbon atom.
- 13. In a bicyclic system, the carbon atoms where the rings are fused together
- 18. A structure corresponding to a local minimum (valley) in an energy diagram
- 19. A reaction in which an amino group is treated with excess methyl iodide, thereby converting it into an excellent leaving group, followed by treatment with a strong base to give an E2 reaction that yields an alkene
- 20. The study of how energy is distributed under the influence of entropy. For chemists, the thermodynamics of a reaction specifically refers to the study of the relative energy levels of reactants and products
- 22. Compounds containing a carbon-carbon triple bond
- 23. A compound that does not rotate plane-polarized light.
- 25. A compound that can serve as a proton acceptor.
- 26. A compound that possesses a hydroxyl group (OH) connected to an sp3-hybridized carbon atom.
- 27. A solution containing equal amounts of both enantiomers
- 28. A compound capable of functioning as an electron-pair donor.
Down
- 1. A conformation in which a hydrogen atom and a leaving group are separated by a dihedral angle of approximately 180°.
- 3. In addition reactions, the observation that the hydrogen atom is generally placed at the vinylic position already bearing the larger number of hydrogen atoms.
- 4. A reaction that involves the addition of X2 (either Br2 or Cl2) across an alkene
- 6. The more substituted product (alkene) of an elimination reaction
- 8. An electron-rich molecule or ion that is capable of donating a pair of electrons.
- 9. A compound that can serve as a proton donor
- 10. A compound that possesses chiral centers and an internal plane of symmetry
- 11. A reaction in which the C═C bond of an alkene is cleaved to form two C═O bonds
- 12. A reaction in which the configuration of the product is dependent on the configuration of the starting material.
- 14. A compound capable of functioning as an electron-pair acceptor.
- 15. A lone pair or charge that is participating in resonance
- 16. The lowest energy conformation for cyclohexane, in which all bond angles are fairly close to 109.5° and all hydrogen atoms are staggered
- 17. A bimolecular nucleophilic substitution reaction.
- 21. A carbanion with the structure RMgX
- 24. A conformation in which a hydrogen atom and a leaving group are approximately coplanar
- 29. An addition reaction in which two groups are installed on opposite sides of a π bond.