Organic Chemistry

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Across
  1. 1. randomness
  2. 3. stereoisomeric structures which do not mirror images of one another
  3. 6. has a hydroxyl group directly bonded to an alkene
  4. 8. stabilizing interaction that results from the interaction of the electrons in a sigma-bond with an adjacent empty or partially filled p-orbital or a π-orbital to give an extended molecular orbital that increases the stability of the system
  5. 9. a term that may be applied to any asymmetric object or molecule
  6. 11. Aldehyde and an Alcohol that is catalytic
  7. 12. occurs within a molecule
  8. 15. an equimolar mixture of the two enantiomeric isomers of a compound, equal chance of adding to top or bottom
  9. 18. rule that whenever it is possible, an elimination reaction will favor the formation of the most stable double bond
  10. 19. The effect on electron density in one portion of a molecule due to electron-withdrawing or electron-donating groups elsewhere in the molecule
  11. 20. deprotonated anions of enols
  12. 22. increase in number of bonds between atoms that are less electronegative
  13. 23. the addition of the elements of water to a substance
  14. 24. any effect due to the size of atoms or groups
  15. 25. interconvert with one another
  16. 26. reactant that donates electrons to form a new bond
  17. 28. a reactant that accepts electrons to form a new bond
Down
  1. 2. neutral dipolar molecule containing a negatively charged atom directly attached to a positively charged heteroatom
  2. 4. when a lone pair is next to an empty p-orbital
  3. 5. if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change to reestablish an equilibrium
  4. 7. stability
  5. 10. a conformation in which substituents on two attached saturated carbon atoms overlap when viewed as a Newman projection
  6. 13. not chiral. A compound (or object) that is superimposable on its mirror image
  7. 14. preparation of two pure enantiomers from a single chiral carbon
  8. 16. occurs between multiple molecules
  9. 17. a substance that, when added to a reaction mixture, changes the rate of attainment of equilibrium in the system without itself undergoing a permanent chemical change
  10. 21. carbon atom gains bonds to more electronegative elements
  11. 27. a set of rules that determines whether a compound is aromatic or not