Organic Chemistry

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Across
  1. 2. a compound containing one or more organic substituents bonded to a nitrogen atom, RNH2, R2NH, R3N.
  2. 4. an organomagnesium halide, RMgX.
  3. 5. a solvent that that contains an H on a N, O, or X.
  4. 6. a compound that contains chirality centers but is nevertheless achiral because it contains a plane of symmetry.
  5. 8. planning an organic synthesis by working backward from the final product to the starting material.
  6. 13. a substance that is used to start a radical chain reaction
  7. 14. an effect observed in NMR that causes a nucleus to absorb toward the left side of the chart. . it is caused by a withdrawal of electron density from the nucleus.
  8. 16. an electron rich species that donates an electron pair to an electrophile.
Down
  1. 1. a substance that contains a trivalent negatively charged carbon atom (R3C:-).
  2. 3. an electron interaction that results from overlap of a vacant P orbital on one atom with as neighboring C-H sigma bond.
  3. 7. what occurs when two reactants exchange parts to give two new products.
  4. 8. a species that has an odd number of electrons.
  5. 9. the right hand portion of an NMR chart
  6. 10. a compound with on –OH group directly bonded to an aromatic ring.
  7. 11. describes the product of an E2 reaction where the more highly substituted alkene is the major product.
  8. 12. a compound with an –OH group bonded to a saturated , sp3-hybridized carbon, ROH.
  9. 15. a compound containing the –CO2R functional group.