Orgabic Reaction Mechanisms

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Across
  1. 5. Formation of the less substituted alkene
  2. 8. A type of nucleophilic substitution where the nucleophile is a solvent molecule
  3. 12. When the reaction chooses one product over the other
  4. 13. The more substituted halide is formed from the addition of H-X to an alkene
  5. 15. Replacement of one group by another
  6. 16. Where carbocations with filled C-H bonds overlap with empty 2p orbitals
  7. 17. Step where two radicals combine
  8. 18. Branch of chemistry which deals with the spatial arrangement of atoms and groups in molecules
  9. 20. The radical forming step
  10. 22. A type of elimination where the most substituted alkene predominates due to hyperconjugation stabilising the transition state
Down
  1. 1. The preferential formation of one isomer over the other
  2. 2. Front side approach, the tetrahedral umbrella would be retained
  3. 3. Disubstituted on adjacent (1,2) positions
  4. 4. When more than one orientation is possible in the product
  5. 6. Donates a pair of electrons
  6. 7. When two substituents are removed from a molecule during a mechanism
  7. 9. Radical reaction and radical regenerations
  8. 10. Nucleophile approaches from the rear of the departing atom, the tetrahedral umbrella is inverted
  9. 11. Consists of a single molecule
  10. 12. A mixture that contains both enantiomers of a compound which are present in equal amounts
  11. 14. Addition of a proton to a molecule
  12. 19. The slowest step of a chemical reaction that determines the speed the overall reaction proceeds at
  13. 21. Step by step sequence of reactions