Aldehydes, Ketones, Carboxylic Acids

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Across
  1. 4. Organomagnesium reagent adding to ketones to form tertiary alcohols.
  2. 9. Simplest aldehyde, often used as a preservative.
  3. 10. Carbonyl functional group written as R–CO–R, bonded to two carbons.
  4. 11. Simplest ketone and common organic solvent.
  5. 15. Reaction converting R–CHO → R–COOH with common oxidants.
  6. 17. Functional group –COOH, carbonyl + hydroxyl.
  7. 18. Product of reaction between an aldehyde and a 1° amine, formed via nucleophilic addition–elimination.
  8. 20. Addition of one alcohol to a ketone before ketal formation.
  9. 21. Alkene cleavage reaction yielding aldehydes under reductive conditions.
  10. 22. Describes the O–H acidity of carboxylic acids relative to alcohols.
  11. 25. Product of aldehyde + 2 equivalents of alcohol under acid catalysis.
  12. 27. Hydrogen-bonded pair of carboxylic acid molecules.
  13. 28. Derivative formed from dehydration of two carboxylic acids.
  14. 29. Reagent that forms a silver mirror when aldehydes are oxidized.
  15. 30. Sodium or potassium salt of long-chain carboxylates.
  16. 31. Step converting R–COOH to a more reactive derivative (e.g., acyl chloride).
Down
  1. 1. Reactive derivative formed from acids using SOCl₂.
  2. 2. Reaction converting ketone → secondary alcohol using hydrides.
  3. 3. Loss of CO₂ from certain carboxylic acids under heat.
  4. 5. Product formed by carboxylic acids or derivatives reacting with amines.
  5. 6. Functional group written as R–CHO, containing a carbonyl bonded to H.
  6. 7. Fundamental reaction mechanism of ketones and aldehydes.
  7. 8. Intermediate formed after nucleophilic attack of one alcohol on an aldehyde.
  8. 12. R–COOH + R′OH → R–COOR′, acid-catalyzed.
  9. 13. Product of nucleophilic addition of HCN to a ketone.
  10. 14. Acylation reaction forming aryl ketones using acid catalysts.
  11. 16. Species that attacks the electrophilic carbonyl carbon of aldehydes.
  12. 19. promoted hydrolysis of esters to form carboxylates and alcohols.
  13. 23. Nucleophilic reducing agent (e.g., NaBH₄) that reduces aldehydes to primary alcohols.
  14. 24. Base-generated α-deprotonated intermediate stabilized by resonance.
  15. 26. Product formed by ketone + 2 equivalents of alcohol under acid.