Across
- 4. Na in liquid NH3 turns an alkyne into a ___ alkene.
- 5. oxidative cleavage, allows aldehyde to be a product
- 7. The pKa of an ____ proton is 25.
- 8. OH ends up on the ___ substituted C when you add aq acid.
- 9. Can NaNH2 deprotonate an alkene?
- 10. Use aqueous ___ to turn an epoxide into a trans diol.
- 12. describes 50/50 mixture of enantiomers
- 14. Two ___ of H2 turn an alkyne into an alkane.
- 17. general term for most alkene reactions
- 18. intermediate in addition of HX
- 19. OH ends up on the ___ substituted C in hydroboration.
- 20. The pKa of an ____ proton is 45.
- 21. reagent used to turn alkene into epoxide
- 23. addition of chlorine across C=C
- 26. addition of bromine across C=C
- 27. addition of H2 across double bond
Down
- 1. H2O attacks the more ___ C in the halonium ion.
- 2. intermediate in reaction with HBr, ROOR
- 3. Hydrogenation involves a ___ addition.
- 5. Halohydrin reaction involves the addition of X and ____.
- 6. addition of OH, H across C=C
- 8. OH ends up on the ___ substituted C in oxymerc-demerc.
- 10. Halogenation involves an _____ addition.
- 11. Halogens end up _____ in a halogenation.
- 13. Hydrogenation product has the hydrogens ____.
- 14. reaction type that produces alkenes
- 15. The pKa of an ____ proton is 50.
- 16. Cold, dilute KMnO4 turns an alkene into a cis ___.
- 22. Use ___'s catalyst to get a cis alkene from an alkyne.
- 24. The addition of HX to an alkene makes an alkyl ____.
- 25. Using HBr, ROOR leads to an _____-Markovnikov product.