Chemical Kinetics

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Across
  1. 3. scientist who related reaction rates to temperature
  2. 11. number of reacting species in an elementary step
  3. 12. short-lived unstable species at the top of the energy barrier
  4. 13. step that removes reactive chain carriers
  5. 14. enzyme kinetics model relating rate to substrate concentration
  6. 16. steps that regenerate reactive intermediates in a chain process
  7. 17. attachment of molecules onto a surface
  8. 18. surface reaction mechanism involving adsorbed reactants
  9. 20. slowest step that controls the overall reaction rate
Down
  1. 1. regime where reaction rate is limited by mass transport
  2. 2. pre-exponential factor in the Arrhenius equation
  3. 4. reaction mechanism involving propagation of reactive intermediates
  4. 5. assumption that an early step reaches equilibrium before rate determining step
  5. 6. highest energy configuration along the reaction coordinate
  6. 7. species formed and consumed during a reaction mechanism
  7. 8. step that generates reactive chain carriers
  8. 9. correction factor accounting for molecular orientation in collisions
  9. 10. release of molecules from a surface
  10. 15. minimum energy required for a chemical reaction to occur
  11. 19. approximation where intermediate concentration remains constant