Fluorite & Perovskite

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Across
  1. 5. alternate name for the fluorite mineral (probably from the french for "blue and yellow")
  2. 8. type of crystal structure with more than 2 atom types
  3. 9. crystal structure with general form ABX3 (CaTiO3); Pm3̅m
  4. 10. bravais lattice for fluorite and perovskite
  5. 11. next-gen nuclear waste immobilization material, extremely low leach rates; based on perovskite structure
  6. 12. heating a material allows electrons trapped in high-energy states to drop down
  7. 15. crystal structure with general form A2X (Li2O)
  8. 16. layered superconductor oxide; must be gradually doped with oxygen
Down
  1. 1. spontaneous electric polarization in the absence of an applied electric field
  2. 2. temperature above which materials lose their permanent polarization; many ferroelectrics have perovskite structure above it
  3. 3. link between electric field and mechanical deformation of the unit cell; PZT is exemplar material; can cause polarization
  4. 4. location oxygen vacancies tend to concentrate; high-energy structural disorder
  5. 6. excited electrons emit energy as light as they return to ground state
  6. 7. crystal structure with general form AX2 (CaF2); Fm3̅m
  7. 13. used as a material for nuclear fuel pellets because of the large central vacancy
  8. 14. decrease in electrical resistance in response to an applied magnetic field; important for microelectronics