Ochem crossword frenzy!

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Across
  1. 2. Addition of water in an anti Markovnikov manner
  2. 4. Going from a secondary carbocation to a tertiary carbocation by a … shift
  3. 6. Compounds with the same molecular formula but different structural formulas
  4. 10. Alcohol in which the hydroxyl group is attached to an end carbon
  5. 13. …’s rule, the basis for this rule is the formation of a more stable carbocation
  6. 16. 3 carbons away (across)
  7. 17. Double Bond
  8. 19. OH Cis
  9. 21. abbreviated, addition of this on the dienophile speeds up the reaction
  10. 25. Creates New C-C bond
  11. 27. Hydrocarbon chain with double bonds
  12. 28. 2 carbon away
  13. 29. 3 membered ring containing an oxygen
  14. 30. reagent the speeds up diels alder reactions
  15. 33. Pd/C, Pt/C, Ni/C
  16. 35. OH Trans
  17. 37. Both enantiomers present
  18. 39. …’s rule saying that the major product of a beta-elimination is the more stable (more highly substituted) alkene
  19. 41. type of arrow that indicates working backwards
  20. 42. Attacking molecule, more electronegative
  21. 44. a specific type of epoxidation where stereochemistry is selective
  22. 45. Addition of water in a Markovnikov manner
  23. 46. the only way to form a cyclohexene in a concerted reaction
  24. 48. Anti Addition
  25. 49. Electron donating groups ( Strong and Weak), speeds up EAS Reaction
  26. 53. conversion of alkene into alkyne
  27. 54. Conjugated Double Bonds
  28. 55. reagent that makes a cis alkene
  29. 56. the nucleophile in a reduction reaction (not carbon related)
Down
  1. 1. conversion of alcohol into ketone
  2. 3. More electrophilic molecule
  3. 5. Electron Withdrawing Groups (Strong and Weak), slows down EAS Reaction
  4. 7. 1 carbon away
  5. 8. reagent with compounds with carbon metal bonds
  6. 9. meta-ChloroPerBenzoicAcid
  7. 11. Electron withdrawing group
  8. 12. Hydrogens are lost from adjacent atoms, resulting in a new pi bond
  9. 14. preference of one direction of bond breaking/making of over other possible directions
  10. 15. An SN2 reaction at a chiral center will … stereochemistry
  11. 18. a specific type of reduction that makes a trans alkene
  12. 20. Alcohol in which the hydroxyl is attached to a carbon attached to two other carbon atoms
  13. 22. (X, OH/OR)
  14. 23. Alkyne with a triple Bond between R and R
  15. 24. DMSO, DMF, hexane, benzene
  16. 26. Alkyne with a triple bond between R and H
  17. 31. conversion of ketone into an alcohol
  18. 32. water, ethanol, acetic acid
  19. 34. 6 carbons with conjugated pi electrons
  20. 36. Unimolecular nucleophilic substitution
  21. 38. O3 breaks alkenes into carbonyls
  22. 40. Bimolecular nucleophilic substitution
  23. 43. (H-X)
  24. 47. Electrophilic Aromatic Substitution
  25. 50. Transformation from enol to carbonyl group
  26. 51. one step, multiple mechanistic arrows
  27. 52. abbreviated, addition of this on the diene speeds up the reaction